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论文 |
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论文题目: |
Scopariusins, A New Class of ent-Halimane Diterpenoids Isolated from Isodon scoparius, and Biomimetic Synthesis of Scopariusin A and Isoscoparin N
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论文题目英文: |
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作者: |
Zhou, Min; Geng, Hui-Chun; Zhang, Hai-Bo; Dong, Ke; Wang, Wei-Guang; Du, Xue; Li, Xiao-Nian; He, Fei; Qin, Hong-Bo; Li, Yan; Pu, Jian-Xin; Sun, Han-Dong
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论文出处: |
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年: |
2013
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卷: |
15 |
期: |
2 |
页: |
314-317 |
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影响因子: |
5.128
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摘要: |
Scopariusins A-C (1-3), three novel rearranged ent-halimanoids with a bicycle[5.4.0]undecane ring system, two new normal ent-halimanoids (4 and 5), and a new ent-clerodanoid (6) were isolated from Isodon scoparius. Moreover, a biomimetic transformation from the ent-clerodanoid to the normal and the rearranged ent-halimane diterpenoids was successfully accomplished, which not only validated the biogenetic hypothesis in this plant but also confirmed the absolute configurations of 1 and 5. |
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